Crystal structure of sodium dihydrogen arsenate

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Crystal structure of sodium di­hydrogen arsenate

Single crystals of the title compound, Na(H2AsO4), were obtained by partial neutralization of arsenic acid with sodium hydroxide in aqueous solution. The crystal structure of Na(H2AsO4) is isotypic with the phosphate analogue and the asymmetric unit consists of two sodium cations and two tetra-hedral H2AsO4- anions. Each of the sodium cations is surrounded by six O atoms of five H2AsO4- groups,...

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Crystal Structure of the Arsenate(V) NaTi2[AsO4]3

The arsenate(V) NaTi2[AsO4]3 has been synthesized by a solid-state reaction route using a salt flux. Its structure has been solved and refined from single-crystal X-ray data: NASICON-type, R3̄c, a = 8.8057(5), c = 22.2406(15) Å, Z = 6, wR(F2) = 0.0617 for 576 unique reflections and 30 variables. The NaTi2[AsO4]3 structure consists of a three-dimensional framework of corner-sharing AsO4 tetrahedr...

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CRYSTAL STRUCTURE OF SODIUM-POTASSIUM .ANTIMONIDE (NaiKSb)

X-ray analysis of Na2KSb a photoemissive material discovered by Sommer has led to the determination of its crystal structure. The unit cell is described by the space group Fm3m-01l5 with four antimony atoms at (0,0,0; O,t,!; t,O,t; t,t,O) + 0,0,0; four potassium atoms at ( ) + t,t,! and eight sodium atoms at ( ) + t,t,t and t,t,t. The crystal structure of Na2KSb has a great resemblance to that ...

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A sodium calcium arsenate, NaCa(AsO4)

The title compound, NaCa(AsO(4)), was synthesized using a hydro-thermal method at 633-643 K. It has a dense structure composed of alternating layers of distorted [CaO(6)] octa-hedra and layers of [AsO(4)] tetra-hedra and distorted [NaO(6)] octa-hedra, stacked along the a axis. The As, Ca and two O atoms lie on the mirror plane at y = 1/4 (i.e. 4c), while the Na atom lies on an inversion centre ...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Crystallographic Communications

سال: 2017

ISSN: 2056-9890

DOI: 10.1107/s2056989017013470